Título alternativo:The v₁/v₃ frequency ratio in tetrahedral oxoanions of the main group elements and the vibrational properties of xenon tetroxide
Resumen
In an earlier work we have theoretically derived and explained certain rules relating the v₁/v₃ frequency ratio of tetrahedral oxoanions of the transition metals with some basic properties of the anions. It is now demonstrated that these rules are also valid for oxoanions of the main group elements of the periodic system. Applying these and other relations it was possible to predict the value of the symmetric stretching frequency v₁ (A₁) of xenon tetroxide. Some vibrational properties of Xe0₄ (force constants, mean amplitudes of vibration, the Coriolis coupling constant and the bond order) are also calculated and compared with those of related species.
Notas
Publicado on line en 2014.
Información general
Fecha de publicación:1972
Idioma del documento:Alemán
Revista:Zeitschrift für Naturforschung A; vol. 27, no. 6
Institución de origen:Facultad de Ciencias Exactas
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