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dc.date.accessioned 2021-07-15T17:04:32Z
dc.date.available 2021-07-15T17:04:32Z
dc.date.issued 1971
dc.identifier.uri http://sedici.unlp.edu.ar/handle/10915/121774
dc.description.abstract The film-growth process occurring on platinum anodes when molten potassium thiocyanate is electrolysed at 190°C has been investigated. The kinetics of the process has been studied by the application of different relaxation techniques. The film growth controls the rate of the process, and its mechanism comprises a surface diffusion process occurring after SCN−-ion oxidation. The film-thickening stage approaches a parabolic growth law. The faradaic rectification of the film is discussed in terms of its physicochemical properties and the actual site where anodic and cathodic reactions take place. en
dc.format.extent 2057-2080 es
dc.language en es
dc.subject Platinum es
dc.subject Kinetics es
dc.subject Molten potassium thiocyanate es
dc.title Kinetics of anodic reactions of molten potassium thiocyanate on platinum en
dc.type Articulo es
sedici.identifier.other https://doi.org/10.1016/0013-4686(71)85019-3 es
sedici.identifier.issn 0013-4686 es
sedici.title.subtitle Formation and growth of anodic film en
sedici.creator.person Calandra, Alfredo J. es
sedici.creator.person Martins, María Elisa es
sedici.creator.person Arvia, Alejandro Jorge es
sedici.subject.materias Ciencias Exactas es
sedici.subject.materias Química es
sedici.description.fulltext true es
mods.originInfo.place Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas es
sedici.subtype Articulo es
sedici.rights.license Creative Commons Attribution 4.0 International (CC BY 4.0)
sedici.rights.uri http://creativecommons.org/licenses/by/4.0/
sedici.description.peerReview peer-review es
sedici.relation.journalTitle Electrochimica Acta es
sedici.relation.journalVolumeAndIssue vol. 16, no. 12 es


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Creative Commons Attribution 4.0 International (CC BY 4.0) Except where otherwise noted, this item's license is described as Creative Commons Attribution 4.0 International (CC BY 4.0)