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dc.date.accessioned 2020-09-15T18:47:34Z
dc.date.available 2020-09-15T18:47:34Z
dc.date.issued 2019
dc.identifier.uri http://sedici.unlp.edu.ar/handle/10915/104717
dc.description.abstract Zn/MCM-41 mesoporous materials have been prepared via classic wet impregnation, employing zinc nitrate as precursor and tested for activity and stability in the Friedel-Crafts alkylation of toluene with benzyl chloride under microwave irradiation and continuous flow. The modified materials were characterized by means of a number of analytical techniques, and surface and textural properties were thoroughly checked. Materials containing the highest Zn loading (15 wt %) provided full conversion after 5 minutes reaction under microwave irradiation (300 W, 120 °C). Materials were proved to be stable and reusable for several cycles with an optimum performance under continuous flow conditions. en
dc.language en es
dc.subject MCM-41 es
dc.subject Friedel-Crafts alkylation es
dc.subject microwave es
dc.subject continuous flow es
dc.subject Zinc es
dc.title Stability and activity of Zn/MCM-41 materials in toluene alkylation: microwave irradiation vs continuous flow en
dc.type Articulo es
sedici.identifier.uri http://hdl.handle.net/11336/97269 es
sedici.identifier.uri https://www.mdpi.com/2073-4344/9/2/136 es
sedici.identifier.other http://dx.doi.org/doi:10.3390/catal9020136 es
sedici.identifier.other hdl:11336/97269 es
sedici.identifier.issn 2073-4344 es
sedici.creator.person Carraro, Paola María es
sedici.creator.person Goldani, Bruna S. es
sedici.creator.person Alves, Diego es
sedici.creator.person Sathicq, Ángel Gabriel es
sedici.creator.person Eimer, Griselda Alejandra es
sedici.creator.person Romanelli, Gustavo Pablo es
sedici.creator.person Luque, Rafael es
sedici.subject.materias Ciencias Exactas es
sedici.subject.materias Química es
sedici.description.fulltext true es
mods.originInfo.place Facultad de Ciencias Exactas es
mods.originInfo.place Centro de Investigación y Desarrollo en Ciencias Aplicadas es
mods.originInfo.place Facultad de Ciencias Agrarias y Forestales es
sedici.subtype Articulo es
sedici.rights.license Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0)
sedici.rights.uri http://creativecommons.org/licenses/by-nc-sa/4.0/
sedici.description.peerReview peer-review es
sedici.relation.journalTitle Catalysts es
sedici.relation.journalVolumeAndIssue vol. 9, no. 2 es


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Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0) Excepto donde se diga explícitamente, este item se publica bajo la siguiente licencia Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0)