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dc.date.accessioned 2020-09-17T21:13:17Z
dc.date.available 2020-09-17T21:13:17Z
dc.date.issued 2017
dc.identifier.uri http://sedici.unlp.edu.ar/handle/10915/104911
dc.description.abstract The photochemistry of methyl thioglycolate (MTG), CH3OC(O)CH2SH, in gas phase and in matrix isolation conditions was studied by means of FTIR spectroscopy, and the influence of the presence of molecular oxygen on the photochemical mechanisms was investigated. The UV–vis broad-band photolysis of MTG in gas phase originates CH3OC(O)CH3 and S8, while in matrix conditions the photoproducts are CH3OH, H2CS, and CO, interacting inside the matrix cage. The photolysis of MTG in the presence of O2 conducts to the formation of SO2, independent of the experimental conditions, being CH3OH, HC(O)OH, and CO the other photoproducts for the gas-phase photolysis, and H2CO, CH4, and CO2 for the experiments performed in Ar matrix conditions. en
dc.format.extent 101-107 es
dc.language en es
dc.subject Photochemistry es
dc.subject IR Spectroscopy es
dc.subject Matrix Isolation es
dc.title Gas-phase and matrix-isolation photochemistry of methyl thioglycolate, CH3OC(O)CH2SH en
dc.type Articulo es
sedici.identifier.other http://dx.doi.org/10.1016/j.jphotochem.2017.05.003 es
sedici.identifier.issn 1010-6030 es
sedici.title.subtitle Influence of the presence of molecular oxygen in the photochemical mechanisms en
sedici.creator.person Bava, Yanina Belén es
sedici.creator.person Tamone, Luciana Mariel es
sedici.creator.person Juncal, Luciana Celeste es
sedici.creator.person Seng, Samantha es
sedici.creator.person Tobón, Yeny A. es
sedici.creator.person Sobanska, Sophie es
sedici.creator.person Picone, Andrea Lorena es
sedici.creator.person Romano, Rosana Mariel es
sedici.subject.materias Química es
sedici.subject.materias Ciencias Exactas es
sedici.description.fulltext true es
mods.originInfo.place Centro de Química Inorgánica es
sedici.subtype Articulo es
sedici.rights.license Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0)
sedici.rights.uri http://creativecommons.org/licenses/by-nc-sa/4.0/
sedici.description.peerReview peer-review es
sedici.relation.journalTitle Journal of Photochemistry and Photobiology A es
sedici.relation.journalVolumeAndIssue vol. 344 es


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Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0) Excepto donde se diga explícitamente, este item se publica bajo la siguiente licencia Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0)