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dc.date.accessioned 2020-10-21T17:46:01Z
dc.date.available 2020-10-21T17:46:01Z
dc.date.issued 2000
dc.identifier.uri http://sedici.unlp.edu.ar/handle/10915/107471
dc.description.abstract The photophysical properties of the Zn salt of octaethylcorrphycene (compound 1) and the doubly protonated octaethylcorrphycene (compound 2) were determined in benzene solutions. Fluorescence spectra and fluorescence quantum yields of ΦF (1) = 0.03 + 0.02 and ΦF (2) = 0.06 + 0.02 were measured. The triplet-triplet absorption spectra were obtained by means of flash-photolysis experiments. The triplet quantum yield values ΦT (1) = 0.79 + 0.08 and ΦT (2) = 0.82 + 0.08 were obtained by using laser-induced optoacoustic spectroscopy. The quantum yield of singlet molecular oxygen generation in air-saturated solutions, ΦΔ (1) = 0.55 + 0.07 and ΦΔ (2) = 0.38 + 0.05, were also measured using time resolved NIR luminescence. en
dc.format.extent 2043-2048 es
dc.language en es
dc.subject Corrphycenes es
dc.subject Fluorescence es
dc.subject Triplet states es
dc.subject Singlet oxygen es
dc.title Photophysical properties of corrphycenes en
dc.type Articulo es
sedici.identifier.other https://doi.org/10.1016/S1386-1425(99)00223-1 es
sedici.identifier.issn 1386-1425 es
sedici.creator.person Mártire, Daniel Osvaldo es
sedici.creator.person Vaveliuk, Pablo es
sedici.creator.person Bilmes, Gabriel Mario es
sedici.subject.materias Química es
sedici.subject.materias Física es
sedici.description.fulltext true es
mods.originInfo.place Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas es
mods.originInfo.place Centro de Investigaciones Ópticas es
sedici.subtype Articulo es
sedici.rights.license Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0)
sedici.rights.uri http://creativecommons.org/licenses/by-nc-sa/4.0/
sedici.description.peerReview peer-review es
sedici.relation.journalTitle Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy es
sedici.relation.journalVolumeAndIssue vol. 56 es


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Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0) Excepto donde se diga explícitamente, este item se publica bajo la siguiente licencia Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0)