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dc.date.accessioned | 2021-05-27T20:14:42Z | |
dc.date.available | 2021-05-27T20:14:42Z | |
dc.date.issued | 1994 | |
dc.identifier.uri | http://sedici.unlp.edu.ar/handle/10915/119361 | |
dc.description.abstract | The underpotential deposition of Cd from dilute aqueous 5 × 10−3 M CdSO4 + 0.5 M Na2SO4 + 0.01 M H2SO4 on Ag electrodeposits grown on polyfaceted Pt single-crystal microspheres was studied using potentiodynamic and potentiostatic techniques, transmission electron diffraction, scanning tunneling microscopy and X-ray photoelectron spectroscopy. Ag electrodeposits were grown in 5 × 10−3 M Ag2SO4 + 0.5 M Na2SO4 + 0.01 M H2SO4 at cathodic overpotentials ηc of −0.06 V and −0.58 V to form a columnar and dendritic Ag surface respectively. Surface rearrangement processes involving the formation of Cd + Ag alloys were studied by stripping voltammetry after the potential was held for a certain time at different preset values covering the potential range in which the degree of surface coverage by Cd atoms was less than or close to unity (θc⩽ 1) on both Ag surfaces. Surface diffusion and penetration of Cd atoms into bulk Ag for θc⩽ 1 are discussed. A place-exchange mechanism is advanced to account for the kinetics of Cd + Ag alloy formation. | en |
dc.format.extent | 141-155 | es |
dc.language | en | es |
dc.subject | Cadmium | es |
dc.subject | Irregular silver electrodeposits | es |
dc.subject | Scanning tunneling microscopy | es |
dc.title | Dynamics of surface alloying promoted by cadmium underpotential deposition-anodic stripping cycles on irregular silver electrodeposits | en |
dc.type | Articulo | es |
sedici.identifier.other | https://doi.org/10.1016/0022-0728(94)03395-1 | es |
sedici.identifier.issn | 1572-6657 | es |
sedici.creator.person | Martins, M. E. | es |
sedici.creator.person | Hernández-Creus, A. | es |
sedici.creator.person | Salvarezza, Roberto Carlos | es |
sedici.creator.person | Arvia, Alejandro Jorge | es |
sedici.subject.materias | Química | es |
sedici.subject.materias | Ciencias Exactas | es |
sedici.description.fulltext | true | es |
mods.originInfo.place | Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas | es |
sedici.subtype | Articulo | es |
sedici.rights.license | Creative Commons Attribution 4.0 International (CC BY 4.0) | |
sedici.rights.uri | http://creativecommons.org/licenses/by/4.0/ | |
sedici.description.peerReview | peer-review | es |
sedici.relation.journalTitle | Journal of Electroanalytical Chemistry | es |
sedici.relation.journalVolumeAndIssue | vol. 375, no. 1-2 | es |