Subir material

Suba sus trabajos a SEDICI, para mejorar notoriamente su visibilidad e impacto

 

Mostrar el registro sencillo del ítem

dc.date.accessioned 2021-06-25T13:51:27Z
dc.date.available 2021-06-25T13:51:27Z
dc.date.issued 1984
dc.identifier.uri http://sedici.unlp.edu.ar/handle/10915/120779
dc.description.abstract Treament of ( + )lim onene with diluted perchloric acid in acetonitrile solution afforded (1S, 5R, 8R) 8-acetam ido-2,4,4.8-tetram ethyl-3-aza-bicyclo[3.3.1]non-2-ene perchlorate while the same reaction on ( — )β-pinene produced the (1S, 5R, 8R) enantiom er, and terpinolene gave the racemic mixture. The structure o f the product is proposed on basis of its physical and spectroscopic (IR , ¹H and ¹³C NMR, MS) properties and its formation involves a Ritter reaction between the monoterpene and acetonitrile. en
dc.format.extent 972-974 es
dc.language en es
dc.subject Ritter Reaction es
dc.subject (+)Limonene es
dc.subject ( -)β-Pinene es
dc.subject Terpinolene es
dc.subject Stereospecific synthesis es
dc.title Ritter Reaction on Terpenoids, I Stereospecific Preparation of (1S,5R,8R) and (1R,5S,8S) 8-Acetamido-2,4,4,8-tetramethyl-3-aza-bicyclo[3.3.1]non-2-ene Perchlorate en
dc.type Articulo es
sedici.identifier.other https://doi.org/10.1515/znb-1984-0722 es
sedici.identifier.issn 1865-7117 es
sedici.creator.person Caram, José Alberto es
sedici.creator.person Martins, María Elisa es
sedici.creator.person Marschoff, Carlos Miguel es
sedici.creator.person Cafferata, Lázaro F. R. es
sedici.description.note Publicado on line en 2014. es
sedici.subject.materias Química es
sedici.description.fulltext true es
mods.originInfo.place Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas es
sedici.subtype Articulo es
sedici.rights.license Creative Commons Attribution-NonCommercial-NoDerivs 3.0 Unported (CC BY-NC-ND 3.0)
sedici.rights.uri http://creativecommons.org/licenses/by-nc-nd/3.0/
sedici.description.peerReview peer-review es
sedici.relation.journalTitle Zeitschrift für Naturforschung B es
sedici.relation.journalVolumeAndIssue vol. 39, no. 7 es


Descargar archivos

Thumbnail
Documento completo
Descargar archivo (2.459Mb) - PDF

Este ítem aparece en la(s) siguiente(s) colección(ones)

Creative Commons Attribution-NonCommercial-NoDerivs 3.0 Unported (CC BY-NC-ND 3.0) Excepto donde se diga explícitamente, este item se publica bajo la siguiente licencia Creative Commons Attribution-NonCommercial-NoDerivs 3.0 Unported (CC BY-NC-ND 3.0)