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dc.date.accessioned | 2021-07-02T15:58:31Z | |
dc.date.available | 2021-07-02T15:58:31Z | |
dc.date.issued | 1995 | |
dc.identifier.uri | http://sedici.unlp.edu.ar/handle/10915/121129 | |
dc.description.abstract | Rough columnar structured gold electrodeposits were prepared in aqueous 0.5 M M H2SO4 by electroreducing a hydrous gold oxide layer built up on a gold substrate by means of a fast periodic potential routine. The analysis of potentiodynamic and potentiostatic hydrous oxide layer electroreduction data indicated the initial nucleation of gold clusters at the metals|oxide interface. The growth of gold nuclei proceeded under a constant capture area condition for depositing gold ions contained in the hydrous oxide layer. Columnar gold electrodeposition was assisted by the gel-like characteristics of the hydrous gold oxide layer. Gold columnar growth ended as soon as the column tips reached the oxide s| solution interfacc. The proposed kinetic model accounts for the high surface area development and surface fractal properties of this type of metal electrode. | en |
dc.format.extent | 133-141 | es |
dc.language | en | es |
dc.subject | Columnar growth | es |
dc.subject | Electroreduction kinetic model | es |
dc.title | Growth of columnar gold electrodes by electroreducing hydrous gold oxide layers | en |
dc.type | Articulo | es |
sedici.identifier.other | https://doi.org/10.1016/0022-0728(94)03843-R | es |
sedici.identifier.issn | 0022-0728 | es |
sedici.title.subtitle | Kinetics and mechanistic interpretation | en |
sedici.creator.person | Vela, María Elena | es |
sedici.creator.person | Marchiano, Susana Lucy | es |
sedici.creator.person | Salvarezza, Roberto Carlos | es |
sedici.creator.person | Arvia, Alejandro Jorge | es |
sedici.subject.materias | Ciencias Exactas | es |
sedici.subject.materias | Química | es |
sedici.description.fulltext | true | es |
mods.originInfo.place | Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas | es |
sedici.subtype | Articulo | es |
sedici.rights.license | Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0) | |
sedici.rights.uri | http://creativecommons.org/licenses/by-nc-sa/4.0/ | |
sedici.description.peerReview | peer-review | es |
sedici.relation.journalTitle | Journal of Electroanalytical Chemistry | es |
sedici.relation.journalVolumeAndIssue | vol. 388, no. 1-2 | es |