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dc.date.accessioned | 2021-08-11T13:07:59Z | |
dc.date.available | 2021-08-11T13:07:59Z | |
dc.date.issued | 2014 | |
dc.identifier.uri | http://sedici.unlp.edu.ar/handle/10915/122482 | |
dc.description.abstract | Five MnOx-CeO2 samples with a molar ratio Mn-Ce between 0 and 100% were obtained by coprecipitation. The samples, which were called 10/0, 7/3, 5/5, 3/7, 0/10, were characterized by XRD, FTIR, XPS, specific surface area and TPR. Phenol was selected as pollutant. The adsorption of phenol from aqueous solution on Mn-Ce samples was investigated in a batch reactor at 25 and 50° C. The adsorption isotherms were described by Langmuir and Freundlich isotherm models and both model fitted. The characterization results showed the formation of solid solution where Mn3+ replaces Ce4+. The most active solid was Mn-Ce 7/3. The results showed that the adsorption process is a function of the Mn-Ce composition. Thermodynamics parameters ΔG0, ΔH0 and ΔS0 were calculated. These parameters indicated that the adsorption of phenol onto Mn-Ce was spontaneous and exothermic at 25 and 50 °C. | en |
dc.format.extent | 166-171 | es |
dc.language | en | es |
dc.subject | Adsorption | es |
dc.subject | Phenol | es |
dc.subject | MnOx-CeO2 | es |
dc.title | Synthesis, Characterization and Study of Phenol Adsorption Over MnOx- CeO2 | en |
dc.type | Articulo | es |
sedici.identifier.other | http://dx.doi.org/10.2174/2211544702666131224233506 | es |
sedici.identifier.issn | 2211-5455 | es |
sedici.creator.person | D'Alessandro, Oriana | es |
sedici.creator.person | Thomas, Horacio Jorge | es |
sedici.creator.person | Sambeth, Jorge Enrique | es |
sedici.subject.materias | Química | es |
sedici.description.fulltext | true | es |
mods.originInfo.place | Centro de Investigación y Desarrollo en Ciencias Aplicadas | es |
sedici.subtype | Articulo | es |
sedici.rights.license | Creative Commons Attribution 4.0 International (CC BY 4.0) | |
sedici.rights.uri | http://creativecommons.org/licenses/by/4.0/ | |
sedici.description.peerReview | peer-review | es |
sedici.relation.journalTitle | Current Catalysis | es |
sedici.relation.journalVolumeAndIssue | vol. 3 | es |