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dc.date.accessioned 2021-08-27T14:02:39Z
dc.date.available 2021-08-27T14:02:39Z
dc.date.issued 2009-09-09
dc.identifier.uri http://sedici.unlp.edu.ar/handle/10915/123610
dc.description.abstract Mass spectrometry is used to evaluate the occurrence of the nitrile-ketenimine tautomerism. Mass spectra of two differently substituted nitriles, ethyl-4,4-dicyano-3-methyl-3-butenoate and diethyl-2-cyano-3-methyl-2-pentenodiate are examined looking for common mass spectral behaviors. Ion fragmentation assignments for specific tautomers allow to predict the presence of the corresponding structures. Additionally, the mass spectrum and nuclear magnetic resonance spectra of ethyl-4,4-dicyano-2,2-diethyl-3-methyl-3-butenoate and that of the corresponding amination product support the occurrence of the ketenimine tautomer in the equilibrium. en
dc.format.extent 1-18 es
dc.language en es
dc.subject Mass spectrometry es
dc.subject Nitrile-Ketenimine Tautomerism es
dc.title Spectrometric Study of the Nitrile-Ketenimine Tautomerism en
dc.type Articulo es
sedici.identifier.other doi:10.1155/2009/408345 es
sedici.identifier.issn 1687-9449 es
sedici.identifier.issn 1687-9457 es
sedici.creator.person Saraví Cisneros, Hebe es
sedici.creator.person Laurella, Sergio Luis es
sedici.creator.person Ruiz, Danila Luján es
sedici.creator.person Ponzinibbio, Agustín es
sedici.creator.person Allegretti, Patricia Ercilia es
sedici.creator.person Furlong, Jorge Javier Pedro es
sedici.subject.materias Ciencias Exactas es
sedici.description.fulltext true es
mods.originInfo.place Laboratorio de Estudio de Compuestos Orgánicos es
sedici.subtype Articulo es
sedici.rights.license Creative Commons Attribution 4.0 International (CC BY 4.0)
sedici.rights.uri http://creativecommons.org/licenses/by/4.0/
sedici.description.peerReview peer-review es
sedici.relation.journalTitle International Journal of Spectroscopy es
sedici.relation.journalVolumeAndIssue vol. 2009 es

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Creative Commons Attribution 4.0 International (CC BY 4.0) Except where otherwise noted, this item's license is described as Creative Commons Attribution 4.0 International (CC BY 4.0)