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dc.date.accessioned | 2021-09-03T12:23:58Z | |
dc.date.available | 2021-09-03T12:23:58Z | |
dc.date.issued | 2011 | |
dc.identifier.uri | http://sedici.unlp.edu.ar/handle/10915/124076 | |
dc.description.abstract | This paper reports a productive discussion of bonding principles in the non-metallic 2nd row hydrides. It suggests the inversion of a bonding character, potentially from hydrides of B & C, which may display unsaturation and electronic deficiency accompanied by electronic delocalization in 1D or 2D or 3D. Contrasted with the opposite possibility, within the finite number of hydrides of N, O and F, that display apparently extensive H-bonding and subsequently proton delocalization in 1D and 2D (in HF & ice polymorphs, respectively), and now potentially in 3D in a corresponding hydride of N called Rice's blue material, or perhaps polyimidogen. Where polyimidogen is a crystalline NH lattice that is a polymorph of the ammonium azide structure-type thus. | en |
dc.language | en | es |
dc.subject | Delocalization in 1D-2D & 3D | es |
dc.subject | Hydrides | es |
dc.subject | H-bonding | es |
dc.subject | Resonance | es |
dc.title | On the Hydrides of B, C, N, O and F | en |
dc.type | Articulo | es |
sedici.identifier.other | doi:10.1038/npre.2011.2541.3 | es |
sedici.identifier.issn | 1756-0357 | es |
sedici.creator.person | Bucknum, Michael J. | es |
sedici.creator.person | Castro, Eduardo Alberto | es |
sedici.subject.materias | Química | es |
sedici.description.fulltext | true | es |
mods.originInfo.place | Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas | es |
sedici.subtype | Articulo | es |
sedici.rights.license | Creative Commons Attribution 3.0 Unported (CC BY 3.0) | |
sedici.rights.uri | http://creativecommons.org/licenses/by/3.0/ | |
sedici.description.peerReview | peer-review | es |
sedici.relation.journalTitle | Nature Precedings | es |
sedici.relation.journalVolumeAndIssue | vol. 6 | es |