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dc.date.accessioned 2021-10-19T12:26:08Z
dc.date.available 2021-10-19T12:26:08Z
dc.date.issued 2002-06-20
dc.identifier.uri http://sedici.unlp.edu.ar/handle/10915/126871
dc.description.abstract The title compound, tetrakis(μ-3,4,5-triethoxy­benzoato-κ2O:O′)­bis­[(pyrazine-κN)­rhodium(II)](Rh—Rh), [Rh2(C13H17O5)4(C4H4N2)2], crystallizes on an inversion centre in the triclinic space group P ‾1. The equatorial carboxyl­ate ligands bridge the two RhII atoms, giving a binuclear lantern-like structure. The pyrazine mol­ecules occupy the two axial coordination sites. The phenyl rings are tilted by ca 10° with respect to the attached carboxyl­ate groups. The pyrazine planes have a torsion angle of ca 19° around the Rh—N bond with respect to the plane of the nearer carboxyl­ate group and are not coplanar with the Rh—Rh bond. en
dc.format.extent m393-m395 es
dc.language en es
dc.subject Adduct es
dc.subject Crystal structure es
dc.subject Pyrazine es
dc.subject Carboxylate es
dc.subject Molecule es
dc.subject Triclinic crystal system es
dc.subject Stereochemistry es
dc.subject Crystallography es
dc.subject Ligand es
dc.subject Dihedral angle es
dc.title A pyrazine bis-adduct of a binuclear rhodium(II) carboxylate containing 3,4,5-triethoxybenzoate as the equatorial ligand en
dc.type Articulo es
sedici.identifier.other doi:10.1107/s0108270102009460 es
sedici.identifier.issn 0108-2701 es
sedici.identifier.issn 1600-5759 es
sedici.creator.person Castro, María A. es
sedici.creator.person Chaia, Zulema es
sedici.creator.person Piro, Oscar Enrique es
sedici.creator.person Cukiernik, Fabio D. es
sedici.creator.person Castellano, Eduardo Ernesto es
sedici.creator.person Rusjan, Marcia es
sedici.subject.materias Ciencias Exactas es
sedici.subject.materias Física es
sedici.description.fulltext true es
mods.originInfo.place Instituto de Física La Plata es
sedici.subtype Articulo es
sedici.rights.license Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0)
sedici.rights.uri http://creativecommons.org/licenses/by-nc-sa/4.0/
sedici.description.peerReview peer-review es
sedici.relation.journalTitle Acta Crystallographica Section C Crystal Structure Communications es
sedici.relation.journalVolumeAndIssue vol. 58, no. 7 es


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Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0) Excepto donde se diga explícitamente, este item se publica bajo la siguiente licencia Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0)