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dc.date.accessioned | 2022-03-16T18:18:52Z | |
dc.date.available | 2022-03-16T18:18:52Z | |
dc.date.issued | 2002-11 | |
dc.identifier.uri | http://sedici.unlp.edu.ar/handle/10915/132695 | |
dc.description.abstract | Aromatic hydrocarbons are susceptible to direct acylation by benzoic acids with high yields bearing ortho or para alkyl groups as substituents under Friedel–Crafts reaction conditions. The α-H of the alkyl moiety seems to be responsible for the observed relatively high reaction rates of conversion. Carbanion-like species are proposed as reaction intermediates, which also operate as strong bases in the reaction rate-determining steps. Trapping experiments, deuterium isotopic effects, and kinetics data favor a concerted reaction pathway where proton transfer from the hydrocarbon molecule to a carbanionic intermediate takes place with a simultaneous electrophilic attack of the carbonylic carbon atom. | en |
dc.format.extent | 764-773 | es |
dc.language | en | es |
dc.subject | Deuterium | es |
dc.subject | Aromatic Hydrocarbon | es |
dc.subject | Benzoic Acid | es |
dc.subject | Proton Transfer | es |
dc.subject | Reaction Pathway | es |
dc.title | Mechanism of Aromatic Hydrocarbon Acylation by Substituted Benzoic Acids: A Novel Reaction Pathway | en |
dc.type | Articulo | es |
sedici.identifier.other | doi:10.1023/a:1021626301812 | es |
sedici.identifier.issn | 0023-1584 | es |
sedici.identifier.issn | 1608-3210 | es |
sedici.creator.person | Allegretti, Patricia Ercilia | es |
sedici.creator.person | Bravo, Rodolfo Daniel | es |
sedici.creator.person | Furlong, Jorge Javier Pedro | es |
sedici.subject.materias | Ciencias Exactas | es |
sedici.subject.materias | Química | es |
sedici.description.fulltext | true | es |
mods.originInfo.place | Facultad de Ciencias Exactas | es |
mods.originInfo.place | Laboratorio de Estudio de Compuestos Orgánicos | es |
sedici.subtype | Articulo | es |
sedici.rights.license | Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0) | |
sedici.rights.uri | http://creativecommons.org/licenses/by-nc-sa/4.0/ | |
sedici.description.peerReview | peer-review | es |
sedici.relation.journalTitle | Kinetics and Catalysis | es |
sedici.relation.journalVolumeAndIssue | vol. 43, no. 6 | es |