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dc.date.accessioned | 2022-04-07T13:57:24Z | |
dc.date.available | 2022-04-07T13:57:24Z | |
dc.date.issued | 1994 | |
dc.identifier.uri | http://sedici.unlp.edu.ar/handle/10915/134066 | |
dc.description.abstract | The oxygen electroreduction reaction was studied on two different preferentially oriented ((111)-type and (100)-type and on a conventional polycrystalline (PC) platinum rotating disc electrodes in acid solutions at 30 °C. At low overpotentials, Tafel lines of −0.060 V decade−1 were obtained on the three electrodes in oxygen-saturated 1.0m H2SO4 and 1.0m H2SO4 + y; m K2SO4 (0 ⩽y ⩽ 1). At high over-potentials the usual Tafel slope of -0.120V decade−1 was observed on both (111)-type and PC platinum electrodes in 1.0m H2SO4, whereas a slope of −0.165V decade−1 was found on (100)-type platinum. In oxygen-saturated 1.0m H2SO4 the surface coverage by O-containing adsorbates on (100)-type platinum was greater than on both (111)-type and PC platinum. Rotating ring-disc electrode data showed that a higher amount of H2O2 was produced on (100)-type platinum than on the other platinum surfaces. The overpotential against current density plots are influenced by the anion concentration depending on the type of preferentially oriented platinum. | en |
dc.format.extent | 119-125 | es |
dc.language | en | es |
dc.subject | oxygen electroreduction | es |
dc.subject | conventional polycrystalline | es |
dc.title | Electroreduction of molecular oxygen on preferentially oriented platinum electrodes in acid solution | es |
dc.type | Articulo | es |
sedici.identifier.other | doi:10.1007/bf00247782 | es |
sedici.identifier.issn | 0021-891x | es |
sedici.identifier.issn | 1572-8838 | es |
sedici.creator.person | Zinola Sánchez, Carlos Fernando | es |
sedici.creator.person | Castro Luna Berenguer, Ana María del Carmen | es |
sedici.creator.person | Triaca, Walter Enrique | es |
sedici.creator.person | Arvia, Alejandro Jorge | es |
sedici.subject.materias | Física | es |
sedici.subject.materias | Química | es |
sedici.description.fulltext | true | es |
mods.originInfo.place | Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas | es |
sedici.subtype | Articulo | es |
sedici.rights.license | Creative Commons Attribution 4.0 International (CC BY 4.0) | |
sedici.rights.uri | http://creativecommons.org/licenses/by/4.0/ | |
sedici.description.peerReview | peer-review | es |
sedici.relation.journalTitle | Journal of Applied Electrochemistry | es |
sedici.relation.journalVolumeAndIssue | vol. 24, no. 2 | es |