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dc.date.accessioned | 2022-06-14T17:13:50Z | |
dc.date.available | 2022-06-14T17:13:50Z | |
dc.date.issued | 1994 | |
dc.identifier.uri | http://sedici.unlp.edu.ar/handle/10915/137887 | |
dc.description.abstract | Oxygen evolution reaction (o.e.r.) kinetics in NaOH solutions have been studied on both fresh and oxide covered Co50Ni25Si15B10 amorphous alloy (G-16) electrodes. Steady state polarization curves obtained in different aqueous xM NaOH (0.1 ⩽ x ⩽ 4) in the 30–80°C range fulfill Tafel relationships at low overpotentials; the Tafel slope is close to 2.3(RT/F) V dec−1 for both G-16 and oxide coated G-16 electrodes. At high overpotentials, ohmic relationships with slopes becoming increasingly steep, regardless of the NaOH concentration, are observed. In the Tafel region, the reaction order with respect to OH− is near 2. The apparent current density at constant potential, for oxide coated G-16 electrodes, is greater than that for uncoated G-16. The high catalytic activity of the oxide coated G-16 for the o.e.r. is attributed to its spinel-type structure. The kinetics of the o.e.r. at low overpotentials is explained through a mechanism involving a first electron transfer step followed by a rate-determining chemical step. | en |
dc.format.extent | 310-315 | es |
dc.language | en | es |
dc.subject | Oxygen evolution reaction | es |
dc.subject | Tafel relationships | es |
dc.subject | Oxide coated G-16 electrodes | es |
dc.title | Kinetics and mechanism of the oxygen evolution reaction at oxide-coated Co-Ni amorphous alloy electrodes | en |
dc.type | Articulo | es |
sedici.identifier.other | doi:10.1007/bf00242058 | es |
sedici.identifier.issn | 0021-891x | es |
sedici.identifier.issn | 1572-8838 | es |
sedici.creator.person | Kessler, Teresita | es |
sedici.creator.person | Triaca, Walter Enrique | es |
sedici.creator.person | Arvia, Alejandro Jorge | es |
sedici.subject.materias | Ciencias Exactas | es |
sedici.subject.materias | Física | es |
sedici.description.fulltext | true | es |
mods.originInfo.place | Facultad de Ingeniería | es |
mods.originInfo.place | Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas | es |
sedici.subtype | Articulo | es |
sedici.rights.license | Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0) | |
sedici.rights.uri | http://creativecommons.org/licenses/by-nc-sa/4.0/ | |
sedici.description.peerReview | peer-review | es |
sedici.relation.journalTitle | Journal of Applied Electrochemistry | es |
sedici.relation.journalVolumeAndIssue | vol. 24, no. 4 | es |