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dc.date.accessioned | 2022-07-15T19:01:48Z | |
dc.date.available | 2022-07-15T19:01:48Z | |
dc.date.issued | 1987 | |
dc.identifier.uri | http://sedici.unlp.edu.ar/handle/10915/139677 | |
dc.description.abstract | The kinetics of the thermal and photochemical decomposition of aquapentacyanoferrate(III) ion in aqueous solution in the presence ofo-phenanthroline was studied spectrophotometrically. The first-order rate constant (k; ϑ) at 30° C [I=1 M(NaCl)] for the thermal reaction is (1.49±0.13)×10−6 s−1 with ΔH; ≠=(158±7)kJ mol−1 and ΔS≠=(42±4) JK−1 mol−1. The initial quantum yield for the photochemical reaction at pH=7 is independent of the light intensity and is (1.49±0.33)×10−2 mol einstein−1. | en |
dc.format.extent | 174-178 | es |
dc.language | en | es |
dc.subject | photolysis | es |
dc.subject | aquapentacyanoferrate(III) | es |
dc.title | Kinetics of the thermal and photochemical decomposition of aquapentacyanoferrate(III) in aqueous solution | en |
dc.type | Articulo | es |
sedici.identifier.other | doi:10.1007/bf01022350 | es |
sedici.identifier.issn | 0340-4285 | es |
sedici.identifier.issn | 1572-901x | es |
sedici.creator.person | Ronco, Silvia Elisa | es |
sedici.creator.person | Aymonino, Pedro José | es |
sedici.subject.materias | Química | es |
sedici.subject.materias | Ciencias Exactas | es |
sedici.description.fulltext | true | es |
mods.originInfo.place | Centro de Química Inorgánica | es |
sedici.subtype | Articulo | es |
sedici.rights.license | Creative Commons Attribution 4.0 International (CC BY 4.0) | |
sedici.rights.uri | http://creativecommons.org/licenses/by/4.0/ | |
sedici.description.peerReview | peer-review | es |
sedici.relation.journalTitle | Transition Metal Chemistry | es |
sedici.relation.journalVolumeAndIssue | vol. 12, no. 2 | es |