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dc.date.accessioned 2022-09-26T18:14:03Z
dc.date.available 2022-09-26T18:14:03Z
dc.date.issued 1988
dc.identifier.uri http://sedici.unlp.edu.ar/handle/10915/142768
dc.description.abstract The kinetics of complexation of Ni¹¹ by isocitric acid have been studied with the stopped-flow method, at 15, 25 and 35°C, ionic strength 0.20 M (NaClO4) and pH range 4.50–6.35. Under our experimental conditions, two processes are observed: the faster reaction takes place within the millisecond time range and the slower one within a few seconds. .A mechanism is proposed to account for the observed behaviour. The rapid process is associated with the complexation itself and the slow one is associated with the deprotonation. For the latter process, the activation energy was determined. en
dc.format.extent 443-446 es
dc.language en es
dc.subject Physical Chemistry es
dc.subject Nickel es
dc.subject Activation Energy es
dc.subject Inorganic Chemistry es
dc.subject Catalysis es
dc.title Kinetics of complexation of nickel(II) by DL-isocitric acid en
dc.type Articulo es
sedici.identifier.other doi:10.1007/bf01043708 es
sedici.identifier.issn 0340-4285 es
sedici.identifier.issn 1572-901x es
sedici.creator.person Coronel Canaviri, Edgar es
sedici.creator.person Féliz, Mario Rubén es
sedici.creator.person Capparelli, Alberto Luis es
sedici.subject.materias Física es
sedici.subject.materias Química es
sedici.description.fulltext true es
mods.originInfo.place Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas es
sedici.subtype Articulo es
sedici.rights.license Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0)
sedici.rights.uri http://creativecommons.org/licenses/by-nc-sa/4.0/
sedici.description.peerReview peer-review es
sedici.relation.journalTitle Transition Metal Chemistry es
sedici.relation.journalVolumeAndIssue vol. 13, no. 6 es


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Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0) Excepto donde se diga explícitamente, este item se publica bajo la siguiente licencia Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0)