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dc.date.accessioned 2022-11-23T13:27:23Z
dc.date.available 2022-11-23T13:27:23Z
dc.date.issued 2020-07-01
dc.identifier.uri http://sedici.unlp.edu.ar/handle/10915/146230
dc.description.abstract This; is the first report on the Ferrier rearrangement of 2-halo-glycals with; S-nucleophiles. We present herein the selective synthesis of new; 2-iodo-2,3-unsaturated O- and S-glycosides. We obtained in good yields and high; anomeric selectivity α-glycosydes. As a particular behaviour, we also; describe heteroaromatic thio sugar derivatives were the C3 addition was; performed in an alternative mechanism. A complete structure and conformation analysis; by NMR was also presented. en
dc.language en es
dc.subject 2-iodo-glycals es
dc.subject Ferrier rearragement es
dc.subject S-glycosides es
dc.subject NMR; conformations es
dc.title New insights into the reactivity of 2-halo-glycals: Ssynthesis of novel iodinated Oand S-glycosides en
dc.type Articulo es
sedici.identifier.other doi:10.26434/chemrxiv.12584822.v1 es
sedici.creator.person Rojas, Agustín Hugo es
sedici.creator.person Lafuente, María Leticia es
sedici.creator.person Vetere, Virginia es
sedici.creator.person Ponzinibbio, Agustín es
sedici.subject.materias Química es
sedici.description.fulltext true es
mods.originInfo.place Centro de Estudios de Compuestos Orgánicos es
mods.originInfo.place Centro de Investigación y Desarrollo en Ciencias Aplicadas es
sedici.subtype Preprint es
sedici.rights.license Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International (CC BY-NC-ND 4.0)
sedici.rights.uri http://creativecommons.org/licenses/by-nc-nd/4.0/
sedici.relation.journalTitle ChemRxiv es
sedici.relation.journalVolumeAndIssue 2020 es


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Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International (CC BY-NC-ND 4.0) Excepto donde se diga explícitamente, este item se publica bajo la siguiente licencia Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International (CC BY-NC-ND 4.0)