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dc.date.accessioned 2022-11-24T14:59:42Z
dc.date.available 2022-11-24T14:59:42Z
dc.date.issued 2007-07
dc.identifier.uri http://sedici.unlp.edu.ar/handle/10915/146350
dc.description.abstract We report the synthesis, FTIR, Raman and NMR spectroscopic features of bis(triphenylphosphine)iminium and tetrabutylammonium thiosaccharinates, PNP(tsac) and NBu₄(tsac) (tsac: thiosaccharinate anion, PNP: bis(triphenylphosphine)iminium). The molecular structure of the former compound was determined by X-ray diffraction methods. The salt crystallizes in the monoclinic P2₁/n space group with a = 9.6481(9), b = 29.258(3), c = 13.177(2) Å, β = 97.53(1)°, and Z = 4 molecules per unit cell. Slight but significant changes in the bonding structure of the thiosaccharinate anion as compared with those reported for the neutral molecule are observed. en
dc.format.extent 669-675 es
dc.language en es
dc.subject Thiosaccharin es
dc.subject Bis(triphenylphosphine)iminium es
dc.subject IR spectroscopy es
dc.subject NMR spectroscopy es
dc.subject X-Ray structure determination es
dc.title Synthesis and Spectroscopic Characterization of Two New Thiosaccharinate Salts en
dc.type Articulo es
sedici.identifier.other doi:10.1007/s00706-007-0648-8 es
sedici.identifier.issn 0026-9247 es
sedici.identifier.issn 1434-4475 es
sedici.identifier.issn 0343-7329 es
sedici.title.subtitle Molecular Structure of Bis(triphenylphosphine)iminium thiosaccharinate, PNP(tsac) en
sedici.creator.person Dennehy, Mariana es
sedici.creator.person Quinzani, Oscar V. es
sedici.creator.person Mandolesi, Sandra D. es
sedici.creator.person Güida, Jorge Alberto es
sedici.creator.person Echeverría, Gustavo Alberto es
sedici.creator.person Piro, Oscar Enrique es
sedici.subject.materias Física es
sedici.subject.materias Química es
sedici.description.fulltext true es
mods.originInfo.place Centro de Química Inorgánica es
mods.originInfo.place Instituto de Física La Plata es
sedici.subtype Articulo es
sedici.rights.license Creative Commons Attribution 4.0 International (CC BY 4.0)
sedici.rights.uri http://creativecommons.org/licenses/by/4.0/
sedici.description.peerReview peer-review es
sedici.relation.journalTitle Monatshefte für Chemie - Chemical Monthly es
sedici.relation.journalVolumeAndIssue vol. 138, no. 7 es


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Creative Commons Attribution 4.0 International (CC BY 4.0) Excepto donde se diga explícitamente, este item se publica bajo la siguiente licencia Creative Commons Attribution 4.0 International (CC BY 4.0)