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dc.date.accessioned 2022-11-30T14:09:20Z
dc.date.available 2022-11-30T14:09:20Z
dc.date.issued 2009
dc.identifier.uri http://sedici.unlp.edu.ar/handle/10915/146632
dc.description.abstract The thermal decomposition study of 3,3,6,6-tetramethyl-1,2,4,5-tetroxane (acetone cyclic diperoxide) was carried out in 2-methoxyethanol solution in the 130-166 °C temperature range. The overall reaction follows a first-order kinetic law up to at least 75% diperoxide conversion. The activation parameters (ΔH# = 22.5 ± 0.7 kcal⋅mol–1 and ΔS# = -25.6 ± 0.5 cal⋅mol–1⋅K–1) for the unimolecular rupture of the O–O bond in the diperoxide molecule were obtained by measuring the remnant diperoxide at different reaction times by the CG technique. Acetone was detected by GC as the major organic product of the reaction. en
dc.format.extent 1455-1459 es
dc.language en es
dc.subject acetone cyclic diperoxide es
dc.subject diacetone diperoxide es
dc.subject tetroxane es
dc.subject thermolysis es
dc.title Thermal decomposition reaction of 3,3,6,6-tetramethyl- 1,2,4,5-tetroxane in 2-methoxy- ethanol solution en
dc.type Articulo es
sedici.identifier.other doi:10.1007/s10593-010-0449-6 es
sedici.identifier.issn 0009-3122 es
sedici.identifier.issn 1573-8353 es
sedici.creator.person Leiva, Laura A. C. es
sedici.creator.person Romero, Jorge M. es
sedici.creator.person Jorge, Nelly L. es
sedici.creator.person Cafferata, Lázaro F. R. es
sedici.creator.person Gómez Vara, Manuel E. es
sedici.creator.person Castro, Eduardo Alberto es
sedici.subject.materias Ciencias Exactas es
sedici.description.fulltext true es
mods.originInfo.place Facultad de Ciencias Exactas es
mods.originInfo.place Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas es
sedici.subtype Articulo es
sedici.rights.license Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0)
sedici.rights.uri http://creativecommons.org/licenses/by-nc-sa/4.0/
sedici.description.peerReview peer-review es
sedici.relation.journalTitle Chemistry of Heterocyclic Compounds es
sedici.relation.journalVolumeAndIssue vol. 45, no. 12 es


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Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0) Except where otherwise noted, this item's license is described as Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0)