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dc.date.accessioned 2024-03-18T16:43:27Z
dc.date.available 2024-03-18T16:43:27Z
dc.date.issued 2008-05
dc.identifier.uri http://sedici.unlp.edu.ar/handle/10915/163949
dc.description.abstract Benzyl acrylate was polymerized under microwave irradiation using radical initiation (benzoyl peroxide, BP). The effect of the concentration of BP and power irradiation on the conversion, average molecular weights and the polydispersity index (Mw/Mn) were investigated. The ¹H NMR and ¹³C NMR spectra analysis showed tendency to syndiotacticity and branched polymers were obtained at high conversion of reactions. A significant enhancement of the rates of polymerization and similar thermodynamic behavior, as compared with those obtained under thermal conditions was found. en
dc.format.extent 597-604 es
dc.language en es
dc.subject benzyl acrylate es
dc.subject radical polymerization es
dc.subject microwave es
dc.subject chain transfer es
dc.subject viscosity es
dc.title Structure and properties of poly(benzyl acrylate) synthesized under microwave energy en
dc.type Articulo es
sedici.identifier.other https://doi.org/10.1016/j.radphyschem.2007.09.015 es
sedici.identifier.issn 0969-806X es
sedici.creator.person Oberti, Tamara Gisela es
sedici.creator.person Schiavoni, María de las Mercedes es
sedici.creator.person Cortizo, María Susana es
sedici.subject.materias Física es
sedici.subject.materias Química es
sedici.description.fulltext true es
mods.originInfo.place Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas es
mods.originInfo.place Laboratorio de Estudio de Compuestos Orgánicos es
sedici.subtype Articulo es
sedici.rights.license Creative Commons Attribution 4.0 International (CC BY 4.0)
sedici.rights.uri http://creativecommons.org/licenses/by/4.0/
sedici.description.peerReview peer-review es
sedici.relation.journalTitle Radiation Physics and Chemistry es
sedici.relation.journalVolumeAndIssue vol. 77, no. 5 es


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Creative Commons Attribution 4.0 International (CC BY 4.0) Excepto donde se diga explícitamente, este item se publica bajo la siguiente licencia Creative Commons Attribution 4.0 International (CC BY 4.0)