Short and stereoselective synthesis of α-methylene-β-hydroxy-γ-butyrolactone diastereomers

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dc.date.accessioned	2011-12-01T13:32:28Z
dc.date.available	2011-12-01T03:00:00Z
dc.date.issued	2011	es
dc.identifier.uri	http://sedici.unlp.edu.ar/handle/10915/8356
dc.description.abstract	A short synthetic approach allowed the preparation, in two steps, of (3S,4R)- and (3R,4R)-2- methylene-3-hydroxy-4-(hydroxymethyl)-γ-butyrolactones from 2,3-O-(3-pentylidene)-D-glyceraldehyde, with overall yields of 32 % and 9 %, respectively. The structure of these γ-butyrolactones was revised by experimental and theoretical investigations.	es
dc.format.extent	1661-1664	es
dc.language	en	es
dc.subject	antitumoral agents; BLYP/6-31G* theoretical calculation; γ-butyrolactones	es
dc.title	Short and stereoselective synthesis of α-methylene-β-hydroxy-γ-butyrolactone diastereomers	es
dc.type	Articulo	es
sedici.identifier.uri	http://www.latamjpharm.org/resumenes/30/8/LAJOP_30_8_2_8.pdf	es
sedici.title.subtitle	Structures revised by theoretical investigations	es
sedici.creator.person	Díaz, Gaspar	es
sedici.creator.person	Carvalho, Gláucia S.	es
sedici.creator.person	Soares, Flávia R. F.	es
sedici.creator.person	Alcântara, Antônio F. de C.	es
sedici.creator.person	Diaz, Marisa A. N.	es
sedici.subject.materias	Farmacia	es
sedici.description.fulltext	false	es
mods.originInfo.place	Colegio de Farmacéuticos de la Provincia de Buenos Aires	es
sedici.subtype	Comunicacion	es
sedici2003.identifier	ARG-FARM-ART-0000001843	es
sedici.relation.journalTitle	Latin American Journal of Pharmacy	es
sedici.relation.journalVolumeAndIssue	vol. 30, no. 8	es

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