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dc.date.accessioned | 2019-11-21T18:18:09Z | |
dc.date.available | 2019-11-21T18:18:09Z | |
dc.date.issued | 2016 | |
dc.identifier.uri | http://sedici.unlp.edu.ar/handle/10915/85918 | |
dc.description.abstract | A series of bimetallic Pd-Pb catalysts with a constant Pd content of 1 wt% and Pb/Pd atomic ratio from 0 to 1.6 supported on γ-Al2O3 were prepared and used for glycerol oxidation with H2O2 as the oxidizing agent at atmospheric pressure, 45℃ and pH=11. The morphology and dispersion of the catalysts were characterized by scanning electron microscopy-energy dispersive X-ray spectroscopy (SEM-EDX) and transmission electron microscopy (TEM). The presence of an alloy phase in the bimetallic catalyst was detected by X-ray photoelectron spectroscopy (XPS). Glycerol conversion obtained with the monometallic Pd catalyst was 19%, which was increased to 100% with the addition of Pb. The four bimetallic PdPb catalysts were able to oxidize glycerol to dihydroxyacetone (DIHA) and the selectivity to DIHA reached 59%, 58%, 34% and 25% for PdPb0.25, PdPb0.50, PdPb1.00 and PdPb1.60 catalysts, respectively. | en |
dc.format.extent | 1982-1990 | es |
dc.language | en | es |
dc.subject | Bimetallic palladium-lead catalyst | es |
dc.subject | Glyceric acid | es |
dc.subject | Glycerol oxidation | es |
dc.subject | Glycolic acid | es |
dc.subject | Hydrogen peroxide | es |
dc.subject | Palladium | es |
dc.title | Oxidation of glycerol with H2O2 on Pb-promoted Pd/γ-Al2O3 catalysts | en |
dc.type | Articulo | es |
sedici.identifier.other | doi:10.1016/S1872-2067(16)62531-7 | es |
sedici.identifier.other | eid:2-s2.0-84999208624 | es |
sedici.identifier.issn | 0253-9837 | es |
sedici.creator.person | Faroppa, María L. | es |
sedici.creator.person | Musci, Juan José | es |
sedici.creator.person | Chiosso, María Eugenia | es |
sedici.creator.person | Caggiano, Claudia G. | es |
sedici.creator.person | Bideberripe, Hernán Pablo | es |
sedici.creator.person | García Fierro, José L. | es |
sedici.creator.person | Siri, Guillermo Jorge | es |
sedici.creator.person | Casella, Mónica Laura | es |
sedici.subject.materias | Ingeniería Química | es |
sedici.subject.materias | Ciencias Exactas | es |
sedici.description.fulltext | true | es |
mods.originInfo.place | Facultad de Ciencias Exactas | es |
mods.originInfo.place | Centro de Investigación y Desarrollo en Ciencias Aplicadas | es |
mods.originInfo.place | Facultad de Ingeniería | es |
sedici.subtype | Articulo | es |
sedici.rights.license | Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0) | |
sedici.rights.uri | http://creativecommons.org/licenses/by-nc-sa/4.0/ | |
sedici.description.peerReview | peer-review | es |
sedici.relation.journalTitle | Chinese Journal of Catalysis | es |
sedici.relation.journalVolumeAndIssue | vol. 37, no. 11 | es |
sedici.rights.sherpa | * Color: green
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