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dc.date.accessioned | 2021-06-14T17:32:40Z | |
dc.date.available | 2021-06-14T17:32:40Z | |
dc.date.issued | 1986 | |
dc.identifier.uri | http://sedici.unlp.edu.ar/handle/10915/120223 | |
dc.description.abstract | The molecular structure of C7H7SO2CI was determined by X-ray diffraction and refined to R = 0.060 and Rw = 0.053 from 1170 unique reflections. The unit cell is triclinic, P1, with Z = 2, a = 8.528(5), b = 8.214(3), c = 6.306(2) A; a = 95.47(3), ß = 104.41(3), y = 93.08(4)°; V = 424.6(3) ų; u = 6.30 cm⁻¹; δcale = 1.49 Mg. m⁻³; F(000) = 196. The dihedral angle between the benzene ring and the CI-S-C(l) plane [84.3(1)°] is similar to those observed for benzenesulfonyl chlorides where molecular packing results from normal van der Waals interactions [1, 2], The compound has normal bond lengths and angles. Distortion of the benzene ring is in agreement with the predicted σ- and π-effects of substituent groups [3], No significantly short intermolecular distances were found. | en |
dc.format.extent | 1107-1111 | es |
dc.language | en | es |
dc.subject | 4-Methyl Benzenesulfonyl chloride | es |
dc.subject | Molecular structure | es |
dc.title | The Molecular Structure of 4-Methyl Benzenesulfonyl Chloride | en |
dc.type | Articulo | es |
sedici.identifier.other | https://doi.org/10.1515/znb-1986-0908 | es |
sedici.identifier.issn | 1865-7117 | es |
sedici.creator.person | Rigotti, Guillermo | es |
sedici.creator.person | Rivero, Blas Eduardo | es |
sedici.creator.person | Filgueira, Roberto Raúl | es |
sedici.description.note | Publicado on line en 2014. | es |
sedici.subject.materias | Química | es |
sedici.description.fulltext | true | es |
mods.originInfo.place | Facultad de Ciencias Exactas | es |
sedici.subtype | Articulo | es |
sedici.rights.license | Creative Commons Attribution-NonCommercial-NoDerivs 3.0 Unported (CC BY-NC-ND 3.0) | |
sedici.rights.uri | http://creativecommons.org/licenses/by-nc-nd/3.0/ | |
sedici.description.peerReview | peer-review | es |
sedici.relation.journalTitle | Zeitschrift für Naturforschung B | es |
sedici.relation.journalVolumeAndIssue | vol. 41, no. 9 | es |