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Phenomenology related to the kinetics of Kolbe electrosynthesis

Document type: Articulo

Abstract

The Kolbe electrosynthesis on polycrystalline platinum in 1 M acetic acid/1 M potassium acetate electrolyte at 30 ° C was studied by using potentiostatic, low-frequency potentiodynamic and impedance techniques. Reaction products and their distribution as a function of potential were determined. There is a good correspondence in the potential ranges where changes in both stationary and non-stationary kinetic data, electrode resistance, electrode capacitance and reaction products were found. Results confirm the existence of different electrochemical reactions and correspondingly different reaction intermediates in the various Tafel regions.

General information

Issue date: 24 de agosto de 1984
Document language: English
Journal: Journal of Electroanalytical Chemistry and Interfacial Electrochemistry; vol. 172, no. 1-2
Origin: Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas
ISSN: 0022-0728
Pages: 255-264
xmlui.dri2xhtml.METS-1.0.item-dc-subject: Kolbe electrosynthesis ; Kinetics
Subjects: Ciencias Exactas ; Química

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Created: 10 de agosto de 2021
Available since: 10 de agosto de 2021
Please, use one of this identificators(URI) for cite o linking this item:
  • http://sedici.unlp.edu.ar/handle/10915/122408
  • https://doi.org/10.1016/0022-0728(84)80190-4

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    Creative Commons Attribution 4.0 International (CC BY 4.0) Except where otherwise noted, this item's license is described as Creative Commons Attribution 4.0 International (CC BY 4.0)