Subir material

Suba sus trabajos a SEDICI, para mejorar notoriamente su visibilidad e impacto

 

Mostrar el registro sencillo del ítem

dc.date.accessioned 2021-10-07T16:59:22Z
dc.date.available 2021-10-07T16:59:22Z
dc.date.issued 2002-02-13
dc.identifier.uri http://sedici.unlp.edu.ar/handle/10915/126412
dc.description.abstract The title compound, catena-poly[[tetrakis(μ-decanoato-κ2O:O′)diruthenium(II,III)(Ru—Ru)]-μ-octanesulfonato-κ2O:O′], [Ru2(C10H19O2)4(C8H17O3S)], is an octane­sulfonate derivative of the mixed-valence complex diruthenium tetradecanoate. The equatorial carboxyl­ate ligands are bidentate, bridging two Ru atoms to form a dinuclear structure. Each of the two independent dinuclear metal complexes in the asymmetric unit is located at an inversion centre. The octane­sulfonate anion bridges the two dinuclear units through axial coordination. The alkyl chains of the carboxyl­ate and sulfonate ligands are arranged in a parallel manner. The global structure can be seen as infinite chains of polar moieties separated by a double layer of non-polar alkyl groups, without interdigitation of the alkyl chains. en
dc.format.extent m144-m146 es
dc.language en es
dc.subject octanesulfonate es
dc.subject diruthenium tetradecanoate es
dc.subject ruthenium es
dc.title A liquid crystal derived from ruthenium(II,III) and a long-chain carboxylate en
dc.type Articulo es
sedici.identifier.uri http://scripts.iucr.org/cgi-bin/paper?S0108270101021540 es
sedici.identifier.other doi:10.1107/s0108270101021540 es
sedici.identifier.issn 0108-2701 es
sedici.identifier.issn 1600-5759 es
sedici.creator.person Zelcer, Andrés es
sedici.creator.person Chaia, Zulema D. es
sedici.creator.person Cukiernik, Fabio D. es
sedici.creator.person Castellano, Eduardo Ernesto es
sedici.creator.person Piro, Oscar Enrique es
sedici.subject.materias Ciencias Exactas es
sedici.subject.materias Química es
sedici.description.fulltext true es
mods.originInfo.place Facultad de Ciencias Exactas es
sedici.subtype Articulo es
sedici.rights.license Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0)
sedici.rights.uri http://creativecommons.org/licenses/by-nc-sa/4.0/
sedici.description.peerReview peer-review es
sedici.workflowEdited true es
sedici.relation.journalTitle Acta Crystallographica - Section C: Crystal Structure Communications es
sedici.relation.journalVolumeAndIssue vol. 58, no. 3 es


Descargar archivos

Thumbnail
Documento
Descargar archivo (93.98Kb) - PDF
Icon
Enlace externo

Este ítem aparece en la(s) siguiente(s) colección(ones)

Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0) Excepto donde se diga explícitamente, este item se publica bajo la siguiente licencia Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International (CC BY-NC-SA 4.0)