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dc.date.accessioned 2014-06-13T19:00:52Z
dc.date.available 2014-06-13T19:00:52Z
dc.date.issued 2004-11
dc.identifier.uri http://sedici.unlp.edu.ar/handle/10915/36595
dc.description.abstract The mass spectra of ketones can provide valuable information with regards to keto-enol equilibria occurring in the gas phase. Mass spectra of selected ketones and thioketones have been analysed and specific fragmentation assignments have been done to characterised and weigh co-existing keto and enol tautomers. Thioketones are of particular interest due to their tendency to shift the tautomeric equilibrium towards the enethiol form. The predictive value of this methodology is not only supported by the influence of these compound's nature and size of the substituent on these equilibria but also by the good correlation found between the selected fragments abundances ratio and semi-empirical calculation (AM1) of the corresponding heats of tautomerization. en
dc.format.extent 294-300 es
dc.language en es
dc.subject ketone en
dc.subject ketones en
dc.subject thiol derivative en
dc.subject mass spectrometry en
dc.subject equilibrium constant en
dc.subject tautomerism en
dc.subject theoretical calculations en
dc.title Enol and enethiol occurrence for some ketones and thioketones en
dc.type Articulo es
sedici.identifier.uri http://www.mdpi.com/1422-0067/5/11/294 es
sedici.identifier.issn 1422-0067 es
sedici.title.subtitle Mass spectrometry and theoretical calculations en
sedici.creator.person Allegretti, Patricia Ercilia es
sedici.creator.person Schiavoni, María de las Mercedes es
sedici.creator.person Cortizo, María Susana es
sedici.creator.person Castro, Eduardo A. es
sedici.creator.person Furlong, Jorge Javier Pedro es
sedici.subject.materias Ciencias Exactas es
sedici.subject.materias Química es
sedici.description.fulltext true es
mods.originInfo.place Facultad de Ciencias Exactas es
sedici.subtype Articulo es
sedici.rights.license Creative Commons Attribution 3.0 Unported (CC BY 3.0)
sedici.rights.uri http://creativecommons.org/licenses/by/3.0/
sedici.description.peerReview peer-review es
sedici.relation.journalTitle International Journal of Molecular Sciences es
sedici.relation.journalVolumeAndIssue vol. 5, no. 11-12 es


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Creative Commons Attribution 3.0 Unported (CC BY 3.0) Excepto donde se diga explícitamente, este item se publica bajo la siguiente licencia Creative Commons Attribution 3.0 Unported (CC BY 3.0)