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dc.date.accessioned 2019-09-13T12:47:20Z
dc.date.available 2019-09-13T12:47:20Z
dc.date.issued 2013
dc.identifier.uri http://sedici.unlp.edu.ar/handle/10915/81150
dc.description.abstract Substituent, temperature and solvent effects on tautomeric equilibria in several β-ketoamides have been investigated by means of nuclear magnetic resonance spectroscopy (NMR). Keto-enol equilibrium predominates over the amide-imidol one. The relative stability of the individual tautomers and the corresponding equilibrium shifts are explained consider- ing electronic and steric effects and tautomer stabilization via internal hydrogen bonds. In solution, these compounds exist mainly as ketoamide and Z-enolamide tautomers, both presenting intramolecular hydrogen bonds. en
dc.format.extent 138-149 es
dc.language en es
dc.subject β-Ketoamides es
dc.subject Keto-Enol Equilibrium es
dc.title Substituent, Temperature and Solvent Effects on the Keto-Enol Equilibrium in β-Ketoamides: A Nuclear Magnetic Resonance Study en
dc.type Articulo es
sedici.creator.person Laurella, Sergio Luis es
sedici.creator.person González Sierra, Manuel es
sedici.creator.person Furlong, Jorge Javier Pedro es
sedici.creator.person Allegretti, Patricia Ercilia es
sedici.subject.materias Química es
sedici.description.fulltext true es
mods.originInfo.place Facultad de Ciencias Exactas es
mods.originInfo.place Laboratorio de Estudio de Compuestos Orgánicos (LADECOR) es
sedici.subtype Articulo es
sedici.rights.license Creative Commons Attribution 4.0 International (CC BY 4.0)
sedici.rights.uri http://creativecommons.org/licenses/by/4.0/


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Creative Commons Attribution 4.0 International (CC BY 4.0) Excepto donde se diga explícitamente, este item se publica bajo la siguiente licencia Creative Commons Attribution 4.0 International (CC BY 4.0)