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Quadrupole hyperfine interaction and thermal stability of ZrF 4 .3H 2 O

Document type: Articulo

Abstract

The quadrupole hyperfine interaction of ZrF4.3H2O is reported. This compound is observed to dehydrate to ZrF4 at 325 K. Spectra taken on cooling were observed to be time dependent, and the rehydration process involved was investigated at 293, 298 and 302 K. Contrary to what had previously been determined in HfF4.3H2O, no intermediate compound was observed to participate in the reaction investigated, thus confirming structural differences already reported to exist between these isoformulae compounds.

General information

Issue date: 1988
Document language: English
Journal: Hyperfine Interactions; vol. 39, no. 2
Origin: Departamento de Física
ISSN: 0304-3843; 1572-9540
Pages: 181-186
xmlui.dri2xhtml.METS-1.0.item-dc-subject: iso-formulae zirconium ; hafnium
Subjects: Ciencias Exactas ; Física

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Created: 6 de abril de 2022
Available since: 6 de abril de 2022
Please, use one of this identificators(URI) for cite o linking this item:
  • http://sedici.unlp.edu.ar/handle/10915/134043
  • https://doi.org/10.1007/bf02394451

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    Creative Commons Attribution 4.0 International (CC BY 4.0) Except where otherwise noted, this item's license is described as Creative Commons Attribution 4.0 International (CC BY 4.0)